The reason for the orange—and for the wan yellows and sickly grays that followed—is a combination of atmospheric chemistry and the physics of teeny-tiny things.More proximately, the cause was, duh, fires. Many are so big and so hot that they create pyrocumulonimbus clouds, or “fire thunderstorms ,” that send soot and smoke all the way up the atmospheric column, 50,000 feet into the stratosphere. The heat also generated unusual winds that carried smoke from the Sierra Nevadas to the coast. All that gunk literally blocked out the sun. At least, some of the sun—the devilish hue was in the details. “I’ve never seen anything like that. I’ve been to polluted cities, but you never get that deep orange, ominous color,” says Sanaz Vahidinia, a physicist at NASA Ames Research Center who studies aerosols and light scattering. “Usually in polluted cities, it’s this mucky color, more like the sepia color I’m seeing now, maybe a little dimmer. It was really fascinating.”
First, the chemistry side. Smoke is what’s left after something burns, reduced to particles; that might be hydrocarbon molecules or soot, which is just straight-up black carbon. Now, the thing to remember here is that even though unfiltered noontime sunlight looks roughly whitish or whitish-yellow, it actually contains a roughly equal amount of every wavelength of light, from the reddish end of the visible spectrum to the bluish, all mixed up in a subatomic pointillist spray. And even though you’re likely to associate carbon-heavy things like oil or coal with the color black—absorbing light from across the visible spectrum—carbon atoms actually have a preference. They absorb and also scatter more longer-wavelength red hues than shorter-wavelength blues. “The soot particles are absorbing the blue light from the sun, and we don’t see it,” says Mark Marley, a researcher at NASA’s Ames Research Center who studies the atmospheres of planets outside Earth’s solar system. Those particles absorbed or scattered back the blue—but let that Mordorish red-orange through.
That smoke wasn’t the only layer in the sky. A marine layer of moist air slid beneath it—San Francisco’s famous Karl the Fog, creeping in like steamed milk beneath the foam of a third-wave latte. Here’s where some physics creeps in as well. Unlike carbon, water vapor typically absorbs more on the red-orange side of the visible spectrum. But those water molecules, just two hydrogens and an oxygen, are also bigger than most particles in smoke. And in the physics of light scattering, size matters. Down at the scale of a molecule or two, some hundreds of nanometers, light might refract and change direction around a particle or bounce off it and head back the way it came depending on its wavelength. Which is to say, different-sized particles interact differently with different colors of light.